Chem.
30B Name
KEY
Exam #1 please print
March
19, 2003 60
min. 100 points
Some questions have more than one correct answer, but you must give only one.
Points are in square brackets,
e.g. [5].
1. Draw the structure of . . . Draw
structures here
|
[5] a. A
compound with formula C5H10
which can react with Br2 |
|
|
[3] b. A compound with formula C5H10 which will not react with Br2 |
|
|
[5] c. diethyl
disulfide |
|
|
[6] d. trans -2,3-dichloro-2-pentene |
|
2. Fill in the blanks.
[3] a. A compound containing two
carbon-carbon double bonds is called
a
DIENE
[3] b. The addition of water to a double bond is called HYDRAYTION
[3] c. The first product of a reaction
between an aldehyde and an alcohol is called a HEMIACETAL___.
/28
- [8] Give a complete name for
2-chloro-4-isopropylphenol
44. Draw the structure of the major organic products of each of the following
reactions.
a.
[6] 
+ CH3SH
b.
[6]
c.
[6] 
5. [4] a. In the set of compounds below, the one with highest boiling point is _b.
[4] b. The one with lowest boiling point is e.
[4] c. The one with the greatest water solubility is b.
6.[4] a. Draw a simple clear sketch showing three molecules of methanol hydrogen bonding to each other. Use dashed lines (---) to show the hydrogen bonds.
[4] b. Draw a simple clear sketch showing one molecule of methanol hydrogen bonding to three molecules of water.
7. [10] Circle and name all the functional groups in the following compound.
8. [3 each = 12] Label each structure as a hemiacetal,
acetal or neither of these.
|
a. |
b. |
|
c.
acetal |
d.
|
/30